I'm late to the party, but for what it's worth, when I scrape my lye solution into my oils, I use 2 spatulas. One to scrape out practically every last drop from the container (or as close as I can get to every drop), and the other to scape off whatever leftover solution might still be clinging to my first spatula. In the end, it's only natural for a small fraction to get left behind, for it's impossible to be 100% perfect/precise, but that small of an amount is not enough to cause problems in my soap by any means.
Again- it's impossible to do it perfectly, but for what it's worth, this is what I do:
1) First, I place my soaping pot on my scale, tare it out, and weigh the largest amount of my batch oil/fat into the pot. Then I remove the pot from the scale and set it aside.
2) Next, I get out a separate measuring container and place it on the scale, tare it out, and weigh out my next largest oil/fat into it. Then I scrape that out into my main pot using my 2 spatula routine explained above. When done, I place the now empty measuring container back on my scale, which, if all the oil is properly scraped out, should register as weighing zero on the scale.
3) Then I repeat #2 with all the remaining oils in my batch.
I personally don't like keeping my main pot on the scale, taring/pouring, taring/pouring each oil directly into it one right after the other. I used to do that, but as Ngian said, if a little more oil falls into the pot than the amount you intended, it's very difficult to remove that particular oil without also removing some of your other oils....... which happened to me one too many times for me to ever want to do it again. lol
IrishLass