Gryfonmoon, are you trying to make laundry soap or just add washing soda to your Castile? I make laundry soap using 8 oz washing soda, 8 oz borax and 4-5 ounces grated soap (100% lard or tallow 0% SF) and 4-5 qrts water to make a liquid/gel soap. I use vinegar in my rinse to stop the soap scum from building up in my cloths. I don't know if you could add the washing soda to the Castile then use that for your laundry and not have to add the soda when you make the laundry soap.
I did try making CP soap once with baking soda, dissolved in some of the water and added after I added my lye water. I hoped it would help remove odors from my hands but found it was somewhat drying to my hands. I don't know if washing soda would have the same affect or not.