Why is coconut oil so cleansing?

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fillycate

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I am looking for people with actually knowledge of chemistry here. I have noticed for myself that coconut oil isn't just cleansing, it is faster to enter into pretty much every type of chemical reaction in the process of soap making and soap using.

I am wondering if this is because the fatty acid chains are both saturated *and* shorter. They are often called "medium" which leads me to wonder about a fatty acid chain that is both saturated and *short*. And where might short fatty acid chains be found?

I am wondering about the fatty acid chains in goat milk. This is not the easiest thing to find information about. It looks like butter fat has an array of fatty acid chains, some of which are labeled as "short." This makes me wonder, would short saturated chains be even more reactive than the ones in coconut oil? (More cleansing, harder bar, faster to trace, etc.)

According to SoapCalc, goat *tallow* and milk fat are not this way. But then, they might be a blend that includes longer chains. Just trying to understand the principles behind what is observed.
 
Oooo, I may have found the answer to my own question! Or, at least part of it.

1.2. Fatty acid composition in goat milk fat
Average goat milk fat differs in contents of its fatty acids significantly from average cow milk fat, being much higher in butyric (C4:0), caproic (C6:0), caprylic (C8:0), capric (C10:0), lauric (C12:0), myristic (C14:0), palmitic (C16:0), linoleic (C18:2), but lower in stearic (C18:0), and oleic acid (C18:1) (Table 1). Three of the medium chain fatty acids (caproic, caprilyc, and capric) have actually been named after goats, due to their predominance in goat milk. They contribute to 15% of the total fatty acid content in goat milk in comparison to 5% in cow milk (Haenlein, 1993). The presence of relatively high levels of medium chain fatty acids (C6:0 to C10:0) in goat milk fat could be responsible for its inferior flavour (Skjevdal, 1979).

From: The Effect of Fatty Acids in Goat Milk on Health | IntechOpen

So... Goat milk has small saturated fatty acid chains, smaller than those in coconut oil! That means that if the qualities of lauric and myristic acid that make coconut oil so hard and cleansing are due to them being both saturated *and* short, then goat milk will have fatty acid chains that are even more so than coconut milk!
 
Not only that... Fractionated coconut oil is coconut oil that has had the larger fatty chains removed, leaving the ones that are identical to the ones so plentiful in goat milk, that these fatty acids were named after goats!


What Is Fractionated Coconut Oil Good For?

Coconut oil is an incredibly healthy fat.
It's rich in several medium-chain fatty acids that can have powerful effects on your metabolism.
Fractionated coconut oil is made from coconut oil and mainly consists of two medium-chain fatty acids.
It has been marketed as a coconut oil that can stay in liquid form in the fridge.
This is a detailed review of fractionated coconut oil and its health effects.

What is fractionated coconut oil?

Fractionated coconut oil is an oil made from regular coconut oil.
Both regular and fractionated coconut oils are great sources of medium-chain triglycerides (MCTs), providing fatty acids that contain 6 to 12 carbon atoms.
However, their fatty acid composition is vastly different.
While the main fatty acid in coconut oil is the 12-carbon lauric acid (C12), most or all of this fatty acid has been removed from fractionated coconut oil.
The long-chain fatty acids present in coconut oil have also been eliminated.
Thus, the main medium-chain fatty acids (MCFAs) in fractionated coconut oil are:
  • C8: caprylic acid or octanoic acid
  • C10: capric acid or decanoic acid
MCFAs are metabolized differently than other fats.
They're transported directly to the liver from the digestive tract, where they may be used as a quick source of energy. They can also be turned into ketone bodies, which are compounds that may have therapeutic effects in those with epilepsy.
Fractionated coconut oil is tasteless, odorless, and usually more expensive than regular coconut oil.
It's very similar or even identical to MCT oil.
Summary Fractionated coconut oil is made from regular coconut oil and mainly consists of the medium-chain fatty acids caprylic acid (C8) and capric acid (C10).

How is fractionated coconut oil made?

Fractionated coconut oil is produced via a process called fractionation.
Fractionation is used to separate different types of fats that are naturally found in some oils. It's often done to make new products for consumers.
The different melting points of various fats make fractionation possible.
For example, lauric acid and long-chain fatty acids have higher melting points than caprylic acid and capric acid. Therefore, they will become solid sooner when cooled.
The fractionation of coconut oil is carried out by heating the oil above its melting point. Then, it's left to cool, and the solid fraction of the oil is separated from the liquid.
The whole process of fractionation can take several hours.
Summary A process called fractionation is used to produce fractionated coconut oil. This method uses the different melting points of fats to separate them.

Fractionated coconut oil may help you lose weight

A diet high in MCTs, the main component of fractionated coconut oil, may aid weight loss.
Most studies on this effect replaced other fats in the diet with MCTs.
MCTs may help you lose weight because they:
  • reduce hunger and calorie intake
  • help you burn more fat and calories
  • are less likely to be stored as fat
However, the amount of weight lost is generally quite modest.
One review of 13 studies found that MCTs reduced body weight by an average of 1.1 pounds (0.5 kg) over three weeks, compared with other fats.
The authors also noted that about half of these studies were funded by MCT oil producers. Therefore, there is a high risk of bias.
Summary Eating a diet rich in MCTs may lead to modest weight loss by helping you eat less and burn more fat. MCTs are also less likely to be stored as fat.

Other potential health benefits

The MCTs in fractionated coconut oil have been associated with several other health benefits, including:
  • Reduced insulin resistance: One small study found that taking MCTs may reduce insulin resistance and improve other risk factors in people with diabetes and excess weight. More studies are needed to confirm this effect.
  • Epilepsy treatment: Children with epilepsy may benefit from a ketogenic diet enriched with MCTs. Adding the MCTs may allow them to eat more carbs and protein, making the diet easier to stick to.
  • Improved brain function: One study reported that in some people with mild to moderate Alzheimer's disease, MCTs may improve brain function. However, further studies are needed.
Summary The MCTs in fractionated coconut oil have been suggested to enhance exercise performance and improve various health conditions. However, more research is needed.

Most fractionated coconut oils don't contain lauric acid

Lauric acid is a major component of coconut oil. In fact, the oil comprises about 50% lauric acid and is one of the world's richest dietary sources of this saturated fat. Lauric acid has been linked to many health benefits. It may kill harmful bacteria, viruses, and fungi while protecting against various infections. Most fractionated coconut oils do not contain any lauric acid, or only very small amounts of it. Thus fractionated coconut oil doesn’t offer all of the health effects that regular coconut oil does.
Summary Fractionated coconut oil is able to stay in liquid form because its lauric acid has been removed. Thus, the oil does not offer lauric acid’s many health benefits.

How is it used?

Fractionated coconut oil has been marketed under three different names.
You may know it as:
  • Fractionated coconut oil: This oil is mainly used for various household and personal care purposes, such as a moisturizer, hair conditioner, and massage oil.
  • MCT oil: It’s often used as a dietary supplement, with 1–3 tablespoons per day being a common dosage recommendation.
  • Liquid coconut oil: This oil is advertised as an edible cooking oil.
Ultimately, these are the same product that has been marketed for different consumer uses.
Summary Fractionated coconut oil is also marketed as MCT oil and liquid coconut oil, but fundamentally, these are all the same product. Its uses include skin care and cooking.

Safety and side effects

Consuming fractionated coconut oil appears to be safe for most people. However, there have been reports of people experiencing digestive symptoms. These include stomach cramps, diarrhea, and vomiting, and they seem particularly common in children on an MCT-enriched ketogenic diet. Although extremely rare, there have been a few cases of people with coconut and coconut oil allergy. These people may experience adverse reactions when consuming fractionated coconut oil.
Summary Fractionated coconut oil is well tolerated by most people. However, it may cause digestive problems in some cases, as well as adverse symptoms in people who are allergic to coconut products.
The bottom line

Fractionated coconut oil is made by separating the different types of fats in regular coconut oil.
What remains are two medium-chain fatty acids that may lead to modest weight loss and several other health benefits.
While fractionated coconut oil may offer some benefits, it's more processed than the regular kind. Plus, lauric acid, one of the most beneficial fats, has been removed.

From:

https://www.healthline.com/nutrition/fractionated-coconut-oil#weight-loss
 
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