I CPOP to ensure gel. It still needs to cure, though if you ask me.
At best, gelling will cut 2 weeks off of my cure time - not half. What I mean by that is that I let my gelled soaps cure for a minimum of 4 weeks- the amount of time that I've found my gelled soap reaches what I consider to be it's earliest best. My
ungelled soaps don't reach what I consider to be their earliest best until 6 weeks have gone by. To me, cure is more than reaching tongue-neutrality or having excess water evaporate out of the bars. There's something still going on at the molecular level that makes my soap noticably milder and bubblier as the weeks go by.
To CPOP, I soap on the warm side (roughly 125 degreesF), and when the batter is poured into my mold, I set the mold (covered) in a 120 degreeF oven, turn the oven off as soon as I put the soap in it, and then I let it sit there overnight as I go to bed (I normally soap at night right before I go to bed). I unmold and cut the next day, usually about 12 to 18 hours after pour, sometimes sooner.
In the rare times that I soap during the daylight hours, I usually peek in on the soap periodically to check on the progress of gel, and then remove the mold as soon as full gel is achieved, which can take as little as 45 minutes to as much as a few hours, depending.
As far as flashpoints go, I've never experienced any adverse effects in my soap such as it catching on fire or or my scents disappearing, etc... Here are a few good discussions about flashpoints that we've had here on the forum that might be of help:
viewtopic.php?f=1&t=20108&p=179443&hilit=flashpoint#p179443
viewtopic.php?f=1&t=17798&p=160055&hilit=flashpoint#p160055
IrishLass