After reading this post the first time, I decided not to spray alcohol on my next batch of soap. I was using the same recipe as usual, an FO I'd used hundreds of times (Kentish Rain from BB), gelled them like normal etc.
When I uncovered them, there's ash. Not tons, but it's there. I've never had ash before, so I just wanted to see if there was really something to the alcohol thing. So, in my opinion, yes there is.