milky said:
I don't have any idea how much lactic acid it contains and how much extra lye I might need to add to make up for it.
You could do an acid-base titration to determine the amount of NaOH (or KOH) needed to neutralize a given amount of kefir.
Essentially, you’ll want to:
1. Make a NaOH solution of a known concentration. Weigh and record the combined weight of your container, the NaOH solution, and a pipette (that will be used later).
2. Measure out a known amount of kefir into a beaker, add enough distilled water to thin it out, and then stir in 3 drops of phenolphthalein indicator solution.
3. Slowly add (drop-by-drop) the NaOH solution until the kefir turns a light pink color; be sure to stir the kefir while adding the NaOH solution. You might get a localized color change, but if stirring removes the color, keep adding the NaOH solution. Your end point is indicated when the entire kefir solution is a light pink color. At this point, don’t add any more of NaOH solution. Dispose of the neutralized kefir—don’t drink it and don’t soap with it!
4. Weigh the beaker of remaining NaOH solution AND the pipette; subtract that from the combine weight in step 1. The difference is the amount of solution required to neutralize that batch of kefir.
So as an example, if you make a 10% NaOH concentration, and it took 8 g of solution to neutralize 10 g of kefir, you’re math would look like this:
8 g NaOH solution x 0.10 = 0.8 g NaOH
In this example, 10 g of kefir would need 0.8 g dry NaOH (or 8% by weight). Please note that is an example—I have no idea how much NaOH is needed to neutralize your kefir, or any other’s for that matter. You’ll need to do this each time you make soap.
As far as alcohol content. . . . I probably wouldn’t worry too much about it. Adding NaOH to the kefir is going to release a lot of heat and will probably drive some of the alcohol out. I don’t know much about kefir, but milk isn’t that high in sugar (and on average, sugar only yields half its weight in alcohol).