A zap from excess alkali is immediate and unmistakable. Think of burning your tongue on hot coffee -- there's little or no time delay between taking a sip and seriously regretting it. A zap is like that, even if you're cautious and rub your finger on the soap and taste your finger. I got really used to getting zapped with the super-lye-heavy soap I mentioned earlier in this thread. Just a tiny taste is all that's required, at least for me, to tell the difference between zap and no-zap.
If your tongue tingles, burns, or whatever after a delay, the sensation is most likely from something else. In my experience, my FO or EO is often the culprit causing a delayed icky taste.