No, not harder to dissolve, but it will affect it's strength. The more water it absorbs from the environment, the weaker the solution you'll get. Basically it will increase your SF. I have no idea how to test except to weigh the containers. I use KOH about every 2-3 months so it sits a while between uses. I've gotten into the habit of weighing the container right after I've measured out what I need for the recipe then writing it on the side of the container with a sharpie. I also include the date. When I use it next I put it on my scale prior to use and note if the weight has changed. For me, it never changes. I live in approx 12% humidity year round so it's not much of a problem for me. I never weigh my NaOH as I use it routinely and only end up opening the container about 3 times before it's empty.