Yes, that's probably what did it. I do all my soaps in a silicone lined mold but with 100% CO I generally just lightly cover them and keep an eye out for overheating.
Tongue Test/Zap Test - A time-honored test to discern if there is any un-reacted lye left in one's unmolded soap.
In CP, the ideal time to tongue-test is when the unmolded soap is at least 3 days to 1 week old.
In HP, the time to tongue-test is after the gel-stage is complete.
In liquid soap-making, the time to tongue-test is after the paste-stage is complete.
To conduct the test with CP soap, wet your finger in water and rub it on the soap's surface to create a small bit of lather. Then, gingerly touch the lathered finger to only the very tip of your tongue. If you feel an immediate 'zap' or stinging sensation, it means that the saponification reaction is not quite complete and the soap is not safe to use yet. Rinse and spit with water if you feel you need to. Conduct the test again in a few more day's time, repeating in the same manner as needed until no zap can be detected.
To test in HP, stir the hot, gelled batter well, remove a small bit of batter with a spoon, let it cool a bit, and then test in the same manner as you would CP soap.
To test with liquid soap paste, remove a small bit of paste, let cool if you need to, then finish in the same manner as with CP. Once 'zap' is no longer detected, the soap is safe to use. Please don't confuse 'safe-to-use' with 'cured'. Once the soap is safe to use, it will still need to be cured for at least 4 weeks (please see 'Cure' for further info regarding the benefits of cure).
For other information with abbreviations/terms see this post:
http://www.soapmakingforum.com/showthread.php?t=51841