I am not sure the goat milk is the cause, because I made some shampoo bars a few weeks ago with just water and 4 oils (no FO, just tea tree and peppermint EO - neither one is known to discolor) and had a green "rind" around. Now it is almost all gone, with only some isolated blotches on the outside. Will try to take a picture of what it looks like today.
As to Alchemy's theory, once things calm down a bit at work, I am going to make two small test batches, using the same formula and procedure, hopefully to duplicate green rind, etc.
Before:
[attachment=1:izoo3f7n]shampoo bar.jpg[/attachment:izoo3f7n]
After (there is still a tinge of green on the bottom edge):
[attachment=0:izoo3f7n]shampoo bar_after.jpg[/attachment:izoo3f7n]