I just put an article up on my blog about Gelling. It is from way back when I ran a Yahoo forum and it was hot debate then. Fact, I put a mold of soap in my freezer and forgot about it for 4 days. I defrosted it, and while it took longer to get firm (no evaporation of water as it was frozen, lol), it was perfect.
I have a copyrighted article in the Library of congress that I wrote in 2005 on not gelling, a technique I called Low Temperature Cold Process Soap making.
Hope that helps! I used to be a Middle Grade science teacher. It is all about the friction. The hotter your starting temps, the faster the molecules move. The faster they move, the more friction build up. The more friction, the more heat. The more heat leads to the gel stage. So slowing down the friction by reducing temps, leads to non gelled soap, or Low Temp Soapmaking. It saves the top notes of delicate fragrance oils, and really helps preserve the essences of essential oils. Also, reduces the darkening of milk soaps.
Kelly Bloom of
Soapalooza Soap Arts Studio