Hi, I'm completely new to soap making and loving it. I've watched many YouTube videos and read what I can but I have a few questions if anyone could help me. I've made 3 batches with goats milk which I'm very proud of and I think they look ok. I'd like to know, how much essential oil do I use? I've followed measurements as accurately as possible but my soap doesn't smell of much. I'm using safety gear but is it only the water and lye liquid mixture that burns or does the cooler sloppy trace stuff you put in the mould burn too? Also, when washing stuff up and putting the dry soap into storage, I have a slimy film on my hands which is really hard to wash off. Does the finished product leave this slime on your hands and is that a normal part of homemade soap? If I accidentally add the wrong amount of lye, can the finished soap burn anyone who uses it (if I were to give it as gifts etc). I'm struggling to get my head around a mixture that burns eventually being safe enough to use as soap on your skin and can I ever do anything wrong in my soap that could hurt somebody. Thank you. x
Lye by itself is caustic, but when it interacts with other components in the right proportions it becomes something else. In some cases it is mixed only with water and in the right proportions is used in making certain foods. Hominy, one of my favorite ways to eat corn, is made using a weak lye solution. Pretzels are another food often prepared using a weak lye solution.
But the lye solution we use to make soap is a much stronger solution and it is still caustic in raw soap. So until the ingredients are fully saponified, such as when Hot Process soap completes saponification in the cook or a day or two after Cold Process soap finishes the saponification interaction, or sooner if gel is hurried during CPOP (cold process/oven process), the raw soap batter can still cause skin burns.
If raw soap splashes onto your skin, and it is left to sit, the active lye in the raw soap batter will react with the lipids (fats) in your skin, thus causing the lye burn. As long as it is left on the skin, it will continue to interact with the lipids in your skin. At first it feels a bit like an itch, later it starts to feel like a burn. So it is best to rinse it off with plain water, more than a simple rinse, a long rinse to ensure all lye interacts with the water and not with your skin anymore. The burning sensation does not disappear immediately and if it bothers you, ice can help reduce the pain as well as add more water to the area. NEVER use vinegar on your skin that has lye spilled onto it; that will just create an exothermic reaction and lead to more skin damage than if you use plain water.
My question was really, if I do by some chance mix anything wrong or too much, would this cause any reactions in the soap i.e. would my end soap end up burning someone with the lye in it or does it just flake/crumble? I'm really really proud of the batches I've done so far and would love to give them to relatives but with following different recipes etc and being new to it, would any incorrect lye calculations cause it to hurt somebody's skin or after a while does the lye become harmless? That's my worry. With regards to the slimy feel, I wasn't sure which part of the process could cause lye burns. Obviously when it's mixed to water and it gets hot I see that's quite risky and then I've put it into moulds and covered it with towels. Any spills I've wiped with a tissue before cleaning up properly and it's then I've noticed a slippery feel to my hands although never any burning. I haven't made a habit of this, it's just happened once and I wondered if the finished soap had this "film" to it. I've not yet tried any and it's all resting as I only started a few days ago. I'll look into the oils as here in the UK we don't have the same shops but thank you for the help.
So, to address the slick feeling of the hands, that's likely caused by exposure to raw soap while the lye is still caustic. You should still be using gloves at that point. All through the soap making process, from start, though pouring into the mould, through cleaning up the utensils and the workspace. Don't remove them until you are completely done in the soaping workspace.
To address your question about how an error in the amount of lye
ils mixture may affect the end product: That's why we do the ZAP test. See this link:
https://www.soapmakingforum.com/threads/how-to-properly-safely-conduct-the-zap-tongue-test.63199/ in the Lye-Based Forum (not the Beginner forum, like some may expect). If done properly following those instructions, you can determine if your soap is lye heavy or not. If you are unsure of if it is zapping or not, get a 9-volt battery and zap test it. Then you know what you are trying to identify. Don't worry; I've zapped myself with a brand new 9-volt battery and it did not hurt me at all.
There are some threads here at SMF that give information where to purchase supplies in the UK. Here are a few, although I have no idea if the recommendations are all still current in the older threads:
https://www.soapmakingforum.com/threads/good-fragrance-oil-supplier-in-the-uk.60935/
https://www.soapmakingforum.com/threads/soap-kitchen-in-uk.55499/
https://www.soapmakingforum.com/threads/help-based-in-the-u-k-making-cp-soaps.65742/
https://www.soapmakingforum.com/threads/recommended-suppliers-for-the-uk.46037/