The 0.40 rule -- how was it calculated?
ASSUMPTIONS
Assume a basic "full water" soap recipe. Choose a total oil weight of 10 ounces.
A "full water" recipe is based on 38% water as % of oils. If my oil weight is 10 oz, what is the weight of the water?
Water weight, oz = 10 oz oils X 38 / 100 = 3.8 oz (wt)
If using a balanced blend of fats, the lye concentration for a "full water" recipe is usually about 28%. So what is the weight of the NaOH needed?
Here is the algebra that must be solved to get this number:
(X, NaOH wt)/(3.8 oz water + X, NaOH wt) = 28 / 100
X = (0.28 X 3.8 ) / (1 - 0.28 )
The final answer:
X, NaOH weight = 1.48 oz
SUPPORTING INFO
Specific gravity of 28% lye solution is 1.310 (Dow Chemical Co.)
Specific gravity of a typical soaping fat is about 0.92 (various sources)
Conversion from fluid ounces to cubic inches: 1 cu in = 0.554 fl oz (from Spice)
CALCULATIONS
What is the volume of oils?
Weight of oils = 10 wt oz
Volume of oils = 10 wt oz / 0.92 = 10.87 fl oz
What is the volume of the 28% lye solution?
Weight of lye solution = 3.8 wt oz water + 1.48 wt oz NaOH = 5.28 wt oz
Volume of lye solution = 5.28 wt oz / 1.310 = 4.03 fl oz
What is the total volume of soap batter based on 10 ounces (wt) of oils?
Total volume of soap batter = Oil volume + Lye solution volume
Total volume of soap batter, fl oz = 10.87 fl oz + 4.03 fl oz = 14.90 fl oz
Total volume of soap batter, cu in = 14.90 fl oz / (0.554 fl oz/cu in) = 26.87 cu in
RESULTS
A basic "full water" soap recipe using 10 wt oz of oil will fill a mold that has a volume of 26.87 cu in.
That means for every 1 wt oz of oils used in a recipe, the soap batter needs 26.87 / 10 = 2.687 cu in of mold volume.
For any given weight of oil, what volume of mold is needed?
Mold volume, cu in = 2.687 X (Oil, wt oz)
For a given mold volume, what weight of oil is needed?
Oil, wt oz = (Mold volume, cu in) X (1/2.687)
The division problem of 1/2.687 = 0.37 so rewrite the previous equation so it looks more like the "0.40 rule" equation:
Oil, wt oz = 0.37 X (Mold volume, cu in)
CONCLUSIONS
The factor I calculated is 0.37, not 0.40. This means if I had created this rule, I would call it "DeeAnna's 0.37 rule", not the "0.40 rule."
Why was a factor of 0.40 used in the original rule rather than 0.37?
One possibility is perhaps the original person who came up with the "0.40 rule" used slightly different assumptions than I did.
Or perhaps the original person wanted the mold to be a bit larger than needed so the soap batter did not fill the mold right up to the brim. The 0.40 factor increases the mold size a bit -- about 8% -- compared with using 0.37.
If you want some room for a sculptured top on the soap, to allow a lid to be put on the mold and not touch the soap, or just to allow for a bit of error, the 0.40 factor makes sense.